Modelling the Kinetics of a Reaction Involving a Sodium Salt of 1,2,4-Triazole and a Complex Substituted Aliphatic Halide
✍ Scribed by Grénman, H.; Salmi, T.; Mäki-Arvela, P.; Wärnå, J.; Eränen, K.; Tirronen, E.; Pehkonen, A.
- Book ID
- 127277957
- Publisher
- American Chemical Society
- Year
- 2003
- Tongue
- English
- Weight
- 173 KB
- Volume
- 7
- Category
- Article
- ISSN
- 1083-6160
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## Abstract A kinetic study of the thermolysis of 4‐crotyl‐3,5‐diphenyl‐4__H__‐1,2,4‐triazole (**1**) in a melt of the neat compound was performed at temperatures in the range of 260–350 °C. The main products formed were 1‐crotyl‐3,5‐diphenyl‐1__H__‐1,2,4‐triazole (3) and 1‐(1‐methylallyl)‐3,5‐diph
The rate constants for the reactions of 4-halomethyl-3-nitrobenzoic acids, the nonnitro derivatives, and their ethyl esters with arylthiolates were measured at different temperatures. It was found that the retardation in rate constants compared to benzyl halides is due to the electrostatic repulsion