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Modelling of the chromatographic separation of xylose-mannose in ion-exchange resin columns

โœ Scribed by A. M. Wilhelm; G. Casamatta; T. Carillon; L. Rigal; A. Gaset


Publisher
Springer
Year
1989
Tongue
English
Weight
429 KB
Volume
4
Category
Article
ISSN
1615-7605

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โœฆ Synopsis


A mathematical model was proposed for the chromatographic separation of xylose and mannose on an ion-exchange resin in the Pb form: dispersion in the mobile phase, external mass transfer around the particles and internal diffusion were taken into account. Small-scale experiments provided an evaluation of the different parameters. Dispersion in the mobile phase was found to be the predominant phenomenon. The Peclet numbers were calculated by identification in the Laplace domain of the elution profiles. Influence of temperature and initial concentration of the sample were studied.

List of symbols

A m 2 C kg/m 3 C* C(s) -D mZ.s -1 Di f S-1


๐Ÿ“œ SIMILAR VOLUMES


An ion-exchange column chromatographic m
โœ Earl F. Walborg Jr.; Lena Christensson; Sven Gardell ๐Ÿ“‚ Article ๐Ÿ“… 1965 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 549 KB

Methods for the column chromatographic analysis of neutral monosaccharides are based on three principles of separation: adsorption, partition between a water and organic phase, and ion-exchange. The chromatographic separations utilizing carbon columns and other adsorbents have been reviewed by Binkl