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Modeling the interaction of amine bases on isolated and geminal hydroxyl groups on silica

✍ Scribed by Pipsa Hirva; Tapani A. Pakkanen

Book ID
118365376
Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
841 KB
Volume
271
Category
Article
ISSN
0039-6028

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In the course of a study of an additivity scheme for conformational energies of substituted ethanes, 2,3 we were intrigued by the lack of additivity displayed by the haloethanes. Thus, whereas monofluoro-substitution in ethane leads to an increase in experimentally observed barrier from 2.93 to 3.33