## Abstract For Abstract see ChemInform Abstract in Full Text.
Modeling the 1,3-Dipolar Cycloaddition of Nitrones to Vinylboranes in Competition with Boration, Cyclization, and Oxidation Reactions
✍ Scribed by Rastelli, Augusto; Gandolfi, Remo; Sarzi-Amadé, Mirko; Carboni, Bertrand
- Book ID
- 125499237
- Publisher
- American Chemical Society
- Year
- 2001
- Tongue
- English
- Weight
- 348 KB
- Volume
- 66
- Category
- Article
- ISSN
- 0022-3263
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📜 SIMILAR VOLUMES
Glycoconjugated isoxazolidine-fused chlorins and bacteriochlorins were prepared in moderate to good yields by 1,3-dipolar cycloaddition reactions of meso-tetrakis(pentafluorophenyl)porphyrin with glycosyl nitrones.
Examination of the stereochemistry of the nucleophilic addition of a dialkyl phosphite anion to a configurationally and conformationally defined nitrone on the one hand and of the 1,3-dipolar cycloaddition of the same nitrone on the other hand should reveal the direction of approach of both the anio
## Abstract Formal [3 + 3] or [4 + 3] cycloaddition products, resp., are obtained in the title reactions depending on the reaction conditions.