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Modeling of Macrocyclic Ligand Complexes

✍ Scribed by Peter Comba; Bodo Martin

Publisher
John Wiley and Sons
Year
2006
Weight
8 KB
Volume
37
Category
Article
ISSN
0931-7597

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The complex [Fe(imox) (Nmim)~], where imox is a planar bis(iminooxime) macrocyclic ligand and Nmim = N-methyl imidazole, undergoes substitution reactions in the presence of 2,2'bipyridine (bipy), leading to a series of intermediate mixed complexes. The forward and reverse rate constants for the subs