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Modeling of hypervalent configurations, valence alternation pairs, deformed structure, and properties ofa-S anda-As2S3

✍ Scribed by S. A. Dembovskii; A. S. Zyubin; F. V. Grigor’ev

Book ID
110119848
Publisher
Springer
Year
1998
Tongue
English
Weight
131 KB
Volume
32
Category
Article
ISSN
1063-7826

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## Abstract A series of mono‐ and disubstituted diiron complexes [(μ‐pdt)Fe~2~(CO)~5~L] [pdt = 1,3‐propanedithiolato; L = PMe~3~ (2), PMe~2~Ph (3PPh~3~ (4), P(OEt)~3~ (5)] and [(μ‐pdt)Fe~2~(CO)~4~L~2~] [L = PMe~2~Ph (6), PPh~3~ (7), P(OEt)~3~ (8)] were prepared as Fe‐only hydrogenase‐active‐site mo