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Modeling of free-radical polymerization with crosslinking: monoradical assumption and stationary-state hypothesis

✍ Scribed by Zhu, S.; Hamielec, A. E.


Book ID
118039535
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
760 KB
Volume
26
Category
Article
ISSN
0024-9297

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πŸ“œ SIMILAR VOLUMES


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✍ F.E. Powell; B.W. Brooks πŸ“‚ Article πŸ“… 1995 πŸ› Elsevier Science 🌐 English βš– 904 KB

Three modes of operation are considered for the free-radical solution polymerisation of vinyl monomers in semi-batch reactors. By using dimensionless variables and equations, the regions of validity for different assumptions of stationarity are determined. These regions depend on the reactor filling

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Abstraet~Calculations on non-classical systems of the type mentioned in the title have been carried out 'iJsing the treatment described in Part I. As before chain transfer has been neglected. It is shown that the properties of the total pre-effect AMpr ~ are analogous to those previously deduced for

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Al~traet--In earlier studies of the kinetic quantities in non-stationary stages of non-classical free-radical polymerization a relation between the total pre-and after-effects (AMos, AM~, respectively) and the rate coefficients kp kto was proposed. This arose from the results of numerical computatio