Three modes of operation are considered for the free-radical solution polymerisation of vinyl monomers in semi-batch reactors. By using dimensionless variables and equations, the regions of validity for different assumptions of stationarity are determined. These regions depend on the reactor filling
Modeling of free-radical polymerization with crosslinking: monoradical assumption and stationary-state hypothesis
β Scribed by Zhu, S.; Hamielec, A. E.
- Book ID
- 118039535
- Publisher
- American Chemical Society
- Year
- 1993
- Tongue
- English
- Weight
- 760 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0024-9297
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π SIMILAR VOLUMES
Abstraet~Calculations on non-classical systems of the type mentioned in the title have been carried out 'iJsing the treatment described in Part I. As before chain transfer has been neglected. It is shown that the properties of the total pre-effect AMpr ~ are analogous to those previously deduced for
Al~traet--In earlier studies of the kinetic quantities in non-stationary stages of non-classical free-radical polymerization a relation between the total pre-and after-effects (AMos, AM~, respectively) and the rate coefficients kp kto was proposed. This arose from the results of numerical computatio