A new method of speciation by differential pulse polarography (DPP) is described. It is focused on non-labile complexes on the DPP time scale. By solving mass-balance equations -which are written for the labile part of a metal-ligand system -free metal, free ligand and non-labile complex concentrati
✦ LIBER ✦
Modeling of a CdII–N-(2-hydroxyethyl)ethylenediamine system and optimization of stability constants by the use of complex formation curves. A polarographic study at a fixed L:M ratio and varied pH
✍ Scribed by Ignacy Cukrowski
- Publisher
- John Wiley and Sons
- Year
- 1997
- Tongue
- English
- Weight
- 671 KB
- Volume
- 9
- Category
- Article
- ISSN
- 1040-0397
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The ligand picolinic acid was studied with Cd II and Pb II by differential pulse polarography (DPP) at fixed total ligand (L T ) to total metal (M T ) concentration ratios, varied pH at 25 ЊC and an ionic strength of m ¼ 0.1 and 0.5 mol dm ¹3 . The corrected peak potential of an uncomplexed metal io