Modeling gel effect in branched polymer systems: Free-radical solution homopolymerization of vinyl acetate

Modeling of effective crosslinking densi

Modeling of effective crosslinking density of the gel in free-radical copolymerization of vinyl/divinyl monomers

✍ Yingwu Luo; Zhixue Weng; Zhiming Huang; Zuren Pan 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 213 KB 👁 2 views

The concept of effective crosslinking density proposed by Scanlan is extended to heterogeneously crosslinking polymer. A kinetic-statistical model of effective crosslinking density of the gel is developed in free-radical heterogeneously crosslinking polymerization. The model is applied to the vinyl