Modeling for the active site nitrate reductase. Oxidation of the complex [MovO(O2CC(S) CH3Ph)2]− by nitrate and nitrite in methanol

The catalytic reduction of nitrobenzene

The catalytic reduction of nitrobenzene at the [MoVIO2(O2CC(S)(C6H5)2)2]2− complex intercalated in a Zn(II)–Al(III) layered double hydroxide host: A kinetic model for the molybdenum–pterin binding site in nitrate reductase

✍ Antonio Cervilla; Francisco Pérez-Pla; Antonio Ribera; Elisa Llopis; Antonio Dom 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 475 KB 👁 2 views

The heterogeneous reduction of nitrobenzene by thiophenol catalyzed by the dianionic bis(2-sulfanyl-2,2-diphenylethanoxycarbonyl) dioxomolybdate(VI) complex, [Mo VI O 2 (O 2 CC(S)(C 6 H 5 ) 2 ) 2 ] 2Ϫ , intercalated into a Zn(II)-Al(III) layered double hydroxide host [Zn 3Ϫx Al x (OH) 6 ] xϩ , has b