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Model studies of the (6-4) photoproduct photoreactivation: synthesis and photosensitized splitting of uracil oxetane adducts

✍ Scribed by Qinhua H. Song; Xiaoming Hei; Zhixiu Xu; Xiang Zhang; Qingxiang Guo

Book ID: 104266525
Publisher: Elsevier Science
Year: 2003
Tongue: English
Weight: 134 KB
Volume: 31
Category: Article
ISSN: 0045-2068
DOI: 10.1016/s0045-2068(03)00082-8

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✦ Synopsis

Uracil oxetane adducts, which are model compounds for the oxetane intermediates generated during the formation of (6-4) photoproducts or in their photoenzymatic repair, have been synthesized using 1,3-dimethyluracil with carbonyl compounds. On the basis of fluorescence measurements and photolysis experiments, it is demonstrated that the oxetane adducts can be split into the nucleotide base and carbonyl compounds via an electron transfer reaction from photosensitizer. The reaction is more efficient for a stronger electron donor.

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