Model for the lattice vibrations of a crystal of diatomic molecules — II. Quasiharmonic equation of state
✍ Scribed by G.E. Jelinek; A.M. Karo; L.J. Slutsky
- Publisher
- Elsevier Science
- Year
- 1972
- Tongue
- English
- Weight
- 89 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0038-1098
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📜 SIMILAR VOLUMES
The problem of the determination of the vibration-rotation eigenvalue in diatomic molecules is considered. An eigenvalue equation totally independent from the eigenfunction is written for any potential, analytical or numerical. This equation uses uniquely the vibration-rotation canonical functions;
Differences between vibrational and rotational rehsation patterns disappex and similarities are reveaIed by\_trxtsforming from stite to er.ergy distributions\_ This IblIows from the constant state density of both osciilators and rotors and the exponential gap 1zw governing their relaxation A simple.