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Model copolymerization reactions. Evidence against concerted complex addition in reactions of simple alkyl radicals with N-phenylmaleimide and donor olefins

✍ Scribed by Prementine, Glenn S.; Jones, Sharon A.; Tirrell, David A.


Book ID
126795826
Publisher
American Chemical Society
Year
1989
Tongue
English
Weight
878 KB
Volume
22
Category
Article
ISSN
0024-9297

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πŸ“œ SIMILAR VOLUMES


Model copolymerization reactions: Eviden
✍ Atsushi Saito; David A. Tirrell πŸ“‚ Article πŸ“… 1993 πŸ› Elsevier Science 🌐 English βš– 327 KB

Akstraet--Reductive demercuration of alkylmercuric bromides with NaBD 4 was used to generate the 1-butyl and t-butyl radicals in mixtures of N-phenylmaleimide (NPM) and either of the donor olefins 2-chloroethyl vinyl ether (CEVE) or tetrathiafulvalene (TTF). In each case, the major products of the r