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Model chemistry of methane monooxygenases: Synthesis and reactivity of an oxo-bridged diiron(III) complex with a tripod oxygen donor ligand

✍ Scribed by Xudong Feng; StephenJ. Lippard


Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
81 KB
Volume
36
Category
Article
ISSN
0162-0134

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## Abstract The synthesis and crystal structures of three nonheme diiron(III) complexes with a tridentate N,N,O Schiff‐baseligand, 2‐({[2‐(dimethylamino)ethyl]imino}methyl)phenol (HL), are reported. Complexes [Fe~2~OL~2~(NCO)~2~] (1a) and [Fe~2~OL~2~(SAL)~2~]·H~2~O [SAL = __o__‐(CHO)C~6~H~4~O^–^] (