A quantum-mechanical model for dissociative sticking, and scattering of a diatomic molecule witbout energy loss at a solid surface is solved exactly. The potential energy surface consists of two channels coupled by a 'late' separable potential. The dependence of the sticking coefficient so on the in
Model calculations in dynamics at surfaces: the sticking of an atom on a cold solid
โ Scribed by T.B. Grimley
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- English
- Weight
- 304 KB
- Volume
- 177
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
A simple quantum-mechanical model for the sticking, and inelastic scattering of an atom at the surface of a cold solid, with energy loss to either an electron or a phonon system, is solved exactly. The elastic gas-solid potential is a 6 function in front of a hard wall, and the coupling to the excitation system of the solid occurs at the 6 function. The behaviour of the sticking coefficient as the energy E of the incoming atom goes to zero is s=,!Y2, and the strong-coupling limit is also s-to. The full dependence of s on E is exhibited for one parameterization oithe model.
๐ SIMILAR VOLUMES
A nonlinear truncated model, concerning thermodiffusive chaos in gaseous media, has been employed to represent evaporation of a solid body on the basis of nonlinearity at the solid/gas interface. Solid/gas consumption has been described in the cell which is characterized by the wavenumber of the int