✦ LIBER ✦

[Mo(CO)2(′buS′2)2] and [MoCO(PPh3)(′buS′2)2]: CO Coordination at [MoS] Centers Where Mo Is in a High Oxidation State

✍ Scribed by Prof. Dr. Dieter Sellmann; Dipl.-Chem. Franz Grasser; Dr. Falk Knoch; Dr. Matthias Moll

Publisher: John Wiley and Sons
Year: 1991
Tongue: English
Weight: 262 KB
Volume: 30
Category: Article
ISSN: 0044-8249
DOI: 10.1002/anie.199113111

No coin nor oath required. For personal study only.

✦ Synopsis

Carbonyl complexes of metals in high oxidation states are usually unstable['] and therefore rare.['] Can such species occur in nitrogenases? The sulfur-coordinated Mo atoms of the active centers of Fe/Mo nitrogenases are probably in the high oxidation state + I V . [ ~] Nevertheless, they are postulat-

📜 SIMILAR VOLUMES

[Mo(CO)2(‘buS2’)2] und [Mo(CO)(PPh3)(‘bu

[Mo(CO)2(‘buS2’)2] und [Mo(CO)(PPh3)(‘buS2’)2]: CO-Koordination an [Mo-S]-Zentren mit Mo in hohen Oxidationsstufen

✍ Prof. Dr. Dieter Sellmann; Franz Grasser; Dr. Falk Knoch; Dr. Matthias Moll 📂 Article 📅 1991 🏛 John Wiley and Sons 🌐 English ⚖ 381 KB 👁 1 views

Stable Intermediates in the Addition and

Stable Intermediates in the Addition and Elimination of SnBuCl3 at Molybdenum Centers by Cleavage or Formation of an SnCl Bond: Crystal Structure of [Mo(CO)2(PCy3)-(μ-Cl)(μ-S2CPCy3)(BuSnCl2)] · CH2Cl2

✍ Dr. Daniel Miguel; Julio A. Pérez-Martinez; Prof. Dr. Victor Riera; Dr. Santiago 📂 Article 📅 1992 🏛 John Wiley and Sons 🌐 English ⚖ 336 KB 👁 2 views