𝔖 Bobbio Scriptorium
✦   LIBER   ✦

MO study of flavin reduction

✍ Scribed by Murray F. Teitell; J. Lawrence Fox

Book ID
104580702
Publisher
John Wiley and Sons
Year
1982
Tongue
English
Weight
517 KB
Volume
22
Category
Article
ISSN
0020-7608

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✦ Synopsis

Abstract

MINDO/3 calculations have been performed on semiquinone and fully reduced lumiflavins and on hydroperoxy adducts of lumiflavin. Frontier orbital indices were calculated. Reduction of the flavin was studied in bent and planar flavin rings. The results suggest that the planar reduced flavin has a smaller ionization potential than the bent reduced flavin. This could account for the low redox potential of protein‐bound reduced flavins.

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