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MO Calculations on the Insertion Reactions of Vinyl Cations

✍ Scribed by Dr. Herbert Kollmar; Dr. Harry O. Smith

Publisher
John Wiley and Sons
Year
1972
Tongue
English
Weight
285 KB
Volume
11
Category
Article
ISSN
0044-8249

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✦ Synopsis

MO Calculations on the Insertion Reactions of Vinvl Cations[**]

imide (20-30%) is obtained as major product apart from a trace amount of (1 a ) , while from the latter conversion the By Herbert Kollmar and Harry 0. Smith"] only product thus far isolated consists of a high melting (> 300Β°C) crystalline compound, which has not yet been identified.

The chemistry of vinyl cations and related species"] is characterized by rearrangements and additions to unsatu-Table 1. Compounds prepared by the reaction of diphenylacetylene with aromatic nitro compounds and carbon monoxide in the presence of carbonyl rhodium. R 'H-NMR Chemical Shift IR ('CO) S(ppm) [d] ( P) Tcl aromatic methyl ( l a )

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