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Mn(III)-catalyzed Aerobic Oxidation of 3-Alkyl-4-hydroxy-1 H -pyrrol-2(5 H )-ones in the Presence of 1,1-Diarylethenes. Synthesis of Stable 8-Aza-1-hydroxy-2,3-dioxabicyclo[4.3.0]nonan-7-one Framework

✍ Scribed by Haque, Aminul; Nishino, Hiroshi


Book ID
124054489
Publisher
Journal of Heterocyclic Chemistry
Year
2013
Tongue
English
Weight
497 KB
Volume
51
Category
Article
ISSN
0022-152X

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Mn(III)-Induced molecular oxygen trappin
✍ Van-Ha Nguyen; Hiroshi Nishino; Kazu Kurosawa πŸ“‚ Article πŸ“… 1997 πŸ› Elsevier Science 🌐 French βš– 204 KB

Molecular oxygen trapping reaction of alkenes with 2,3-pyrrolidinedione derivatives was developed using a Mn(lll)-induced oxidation system. AIkenes and 2,3-pyrrolidinediones were treated with manganese(Ill) acetate in acetic acid under a stream of dry air, giving l-hydroxy-8-aza-2,3-dioxabicyclo[4.3