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Mn(ii) metal–organic frameworks based on Mn3 clusters: from 2D layer to 3D framework by the “pillaring” approach

✍ Scribed by Chen, Yong-Qiang; Liu, Sui-Jun; Li, Yun-Wu; Li, Guo-Rong; He, Kun-Huan; Chang, Ze; Bu, Xian-He

Book ID
118124993
Publisher
Royal Society of Chemistry
Year
2013
Tongue
English
Weight
983 KB
Volume
15
Category
Article
ISSN
1466-8033

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## Abstract The hydrothermal reactions of Zn(ClO~4~)~2~·6H~2~O/Cu(NO~3~)~2~·6H~2~O with 5‐(4‐pyridyl)tetrazole in an ethanol/water or ethanol/water/pyridine medium yield one 2D and one 3D metal‐organic coordination framework [Zn~2~(OH)(4‐ptz)~3~] (1) and [Cu(4‐ptz)·0.5(py)] (3) [4‐ptz = 5‐(4‐pyridy