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MNDO-PM3 study on gas-phase alkaline hydrolysis of phosphoryl and thiophosphoryl fluorides

✍ Scribed by T. Katagi


Book ID
114141268
Publisher
Elsevier Science
Year
2001
Tongue
English
Weight
119 KB
Volume
538
Category
Article
ISSN
0166-1280

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MNDO-PM3 study on model cytochrome P450-
✍ Toshiyuki Katagi πŸ“‚ Article πŸ“… 1993 πŸ› John Wiley and Sons 🌐 English βš– 718 KB

## Abstract The reaction mechanism of the model cytochrome P450‐mediated desulfuration of thiophosphoryl trifluoride, trimethylphosphine sulfide, and trimethyl phosphorothionate was examined by the semiempirical MNDO‐PM3 molecular orbital method. The proposed pathways, involving initial formation o