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Mn(5−n)/2HnPMOV2 as re-oxidant of palladium(II) in solid Wacker catalysts

✍ Scribed by Nowińska, Krystyna ;Dudko, Donalita


Book ID
105589177
Publisher
Springer
Year
1997
Tongue
English
Weight
263 KB
Volume
61
Category
Article
ISSN
0133-1736

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In the absence of CuC12, ethene was oxidized to ethanal by PdCl,(pyridine) -in aqueous solution by the rate expression: \* where K' is the equilibrium constant for n-complex formation between ethene and PdCl,(Py) -(Py =pyridine). This rate expression is of the same form as that previously found for