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[Mn2(CO)6(.mu.-Ph2PCH2PPh2)]2-(Mn:Mn), a Nucleophilic Unsaturated Binuclear Anion

✍ Scribed by Liu, Xiang-Yang; Riera, Victor; Ruiz, Miguel A.


Book ID
120862083
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
323 KB
Volume
13
Category
Article
ISSN
0276-7333

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Synthesis, Structure, and Reactivity of
✍ Dr. Francisco J. García Alonso; Dr. Manuel García Sanz; Prof. Victor Riera; Dr. 📂 Article 📅 1988 🏛 John Wiley and Sons 🌐 English ⚖ 237 KB 👁 1 views

H,-elimination from 3 must also occur [Eq. (e)]."ll Note that this equilibrium involves the same 16-electron species implicated in Equation (c). The product-forming hydrido-ethyl (A) and hydridoethyl ethylene (B) species (Scheme 1) "downstream" of reaction (d) have not been observed under a variety