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Mn-salen catalyzed asymmetric epoxidation of (±)-3-alkylindene: Reagent-dependent stereoselectivity

✍ Scribed by Yukiko Noguchi; Ryo Irie; Tsutomu Fukuda; Tsutomu Katsuki


Book ID
103408226
Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
262 KB
Volume
37
Category
Article
ISSN
0040-4039

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Asymmetric Mn(III)-salen catalyzed epoxi
✍ Pekka Pietikäinen 📂 Article 📅 1999 🏛 Elsevier Science 🌐 French ⚖ 199 KB

Asymmetric Mn(III)-salen catalyzed epoxidation of simple cis-disubstituted and trisubstituted alkenes in mild conditions was performed using tetrabutylammonium monopersulfate (Bu4NHSO5) as the oxidant together with N-methylmorpholine N-oxide as an additive. Particularly high yields of epoxides (up t