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Mn-containing porous silicates as catalysts for the solvent-free selective oxidation of alkyl aromatics to aromatic ketones with molecular oxygen

✍ Scribed by N. Novak Tušar; S.C. Laha; S. Cecowski; I. Arčon; V. Kaučič; R. Gläser


Book ID
113800156
Publisher
Elsevier Science
Year
2011
Tongue
English
Weight
606 KB
Volume
146
Category
Article
ISSN
1387-1811

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New transition metal substituted silicate xerogels, ML -SiO , have been prepared by the sol-gel technique and have n 2 been used as heterogeneous catalysts for the side-chain oxidation of alkyl arenes with anhydrous t-butylhydroperoxide. The cobalt substituted silicates were the most active and sel