Mizoroki–Heck-Type Reaction Mediated by Potassium tert-Butoxide
✍ Scribed by Prof. Eiji Shirakawa; Dr. Xuejing Zhang; Prof. Tamio Hayashi
- Book ID
- 101543764
- Publisher
- John Wiley and Sons
- Year
- 2011
- Tongue
- English
- Weight
- 297 KB
- Volume
- 123
- Category
- Article
- ISSN
- 0044-8249
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📜 SIMILAR VOLUMES
## Abstract The transition metal free reaction of various aryl halides with excess stilbenes (5 equiv.) proceeds through aryl radical intermediates and the iodides are found to be generally the most effective substrates.
## Abstract Treatment of a mixture of epoxide and styrene with trimethylsilylmethylmagnesium bromide in the presence of a cobalt‐phosphine complex afforded homocinnamyl alcohol in good yield. The reaction should begin with ring opening of the epoxide by the action of magnesium bromide which leads t
## Abstract Reactions of organolithium compounds with alkyl halides and with epoxides are considerably accelerated by addition of equivalent amounts of potassium __tert__‐butoxide.