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Mixed μ-phosphido or μ-thiolato μ-halo-dimolybdenum(III) compounds [Mo2Cp2(μ-SMe)2(μ-X)(μ-Y)] (X = PPh2, Y = Cl; X = SCH3, Y = Br, I): Electrochemical and structural comparisons – The X-ray structure of [{Mo2Cp2Br(μ-O)(μ-SMe)2}2(μ-MoO4)]

✍ Scribed by Christine Le Roy; François Y. Pétillon; Kenneth W. Muir; Philippe Schollhammer; Jean Talarmin


Book ID
108189146
Publisher
Elsevier Science
Year
2006
Tongue
English
Weight
291 KB
Volume
691
Category
Article
ISSN
0022-328X

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Reactions of Ag 4 X 4 (Ph 3 P) 4 (X = Br, I) with 1,3-bis(diphenylphosphine)methane (dppm) ligand under microwave heating conditions afforded two asymmetric silver(I) dimers of the type [Ag 2 (l-X) 2 (ldppm)(PPh 3 ) 2 ], X = Br(1), I(2), with butterfly-shaped dinuclear cores. The molecular structure