Mixed Valency in a Uranium Multimetallic
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Eric J. Schelter; Ruilian Wu; Brian L. Scott; Joe D. Thompson; David E. Morris;
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Article
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2008
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John Wiley and Sons
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English
⚖ 459 KB
The electronic structures of early actinide (Th-Pu) compounds present unique challenges to study because of their very large spin-orbit coupling and appreciable 5f/6d metalligand orbital overlap. In fact, it is the interplay of (non)participating 5f/6d orbitals in bonding that is the primary factor