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Mixed-Valence State of Europium in the Misfit Layer Compound (EuS)1.173NbS2.

✍ Scribed by Laurent Cario; Pierre Palvadeau; Alain Lafond; Catherine Deudon; Yves Moelo; Benoit Corraze; Alain Meerschaut

Publisher: John Wiley and Sons
Year: 2003
Weight: 72 KB
Volume: 34
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200320011

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The new layered mis5t sul5de of the 1.5Q/1H homologue type, (Pb(Mn, Nb) 0.5 S 1.5 ) 1.15 NbS 2 , has been synthesized. Electron probe microanalysis gives the chemical formula (Pb 1.02 Mn 0.33 Nb 0.16 S 1.50 ) 1.15 NbS 2 , indicating Nb incorporation in the rock-salt-type part (Q layer). Its crystal