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Mixed thiocyanate bonding in palladium(II) complexes of bidentate ligands

✍ Scribed by Meek, Devon W.; Nicpon, Philip E.; Meek, Violet I.

Book ID: 120340760
Publisher: American Chemical Society
Year: 1970
Tongue: English
Weight: 1023 KB
Volume: 92
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja00721a011

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The complexes [(PhZdtc)Pd(R,mtc)ZPd(Phzdtc)] , Pd(Rzmtc)(R;dtc)(PPhJ) and Pd(az)(Rzmtc) have been prepared (az = azobenzene-2-C,N; R = methyl, R2 = pyrrolidyl, piperidyl and R ' = phenyl, ethyl, butyl). Infrared data reveal that in the solid state the [(Ph,dtc)Pd(R2mtc)ZPd(PhZdtc)] complexes are di