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Mixed Solvent and Polymer Coordination in PAN and PMMA Gel Polymer Electrolytes Studied by Ab Initio Calculations and Raman Spectroscopy

โœ Scribed by Johansson, Patrik; Edvardsson, Magnus; Adebahr, Josefina; Jacobsson, Per


Book ID
124167857
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
100 KB
Volume
107
Category
Article
ISSN
0022-3654

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Polymer electrolyte poly(ethylene oxide)
โœ Jiล™รญ Spฤ›vรกฤek; Jiล™รญ Dybal ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 100 KB ๐Ÿ‘ 1 views

Solid-state 13 C NMR spectra and ab initio calculations of 13 C NMR chemical shifts show that poly(ethylene oxide) (PEO) carbons in complex with LiCF 3 SO 3 (both in crystalline and amorphous phase) are more shielded in comparison with neat PEO, due to the coordination to the Li + cation. The result