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Mixed ruthenium-rhodium trinuclear complex [Ru2Rh(.mu.3-O)(.mu.-CH3COO)6(L)3]+ (L = H2O or pyridine)

โœ Scribed by Sasaki, Yoichi; Tokiwa, Ayako; Ito, Tasuku


Book ID
126882475
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
935 KB
Volume
109
Category
Article
ISSN
0002-7863

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The 'H NMR spectra of acetate methyl signals of the titled three complexes in CD,OD change with time due to successive substitution of CD,OD for the coordinated water molecules. The first-order rate constants for the first methanol-d., substitution of the triruthenium(II1) and trirhodium(II1) comple