## Symposium abstracts -solute-solute-solvent interactions In benzonitrile the proton transfer rates in reaction (1) are correlated with the equilibrium constants. The fastest observed rates are diffusion controlled. Consequences of the kinetic results for the interpretation of properties of the
Mixed metal complexes in solution. Part I. Potentiometric study of heterobinuclear copper(II)-l-histidinate complexes with nickel(II), zinc(II) and cadmium(II) ions in aqueous solution
β Scribed by Paola Amico; Pier Giuseppe Daniele; Giuseppe Arena; Giorgio Ostacoli; Enrico Rizzarelli; Silvio Sammartano
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- English
- Weight
- 324 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0020-1693
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π SIMILAR VOLUMES
## Abstract Four new ligands, namely the Nβsubstituted 2β(4βsulfonyl)βpyrrylmethyl derivatives of methylamine, glycine, ethylenediamine and iminodiacetic acid, were synthesized to investigate the coordinating tendency of pyrrolic nitrogen in aqueous solution. The complex formation of these ligands
Homo-and heterobinuclear complexes of copper(II) nickel(II) and zinc(II) with diethylenetriamine and imidazole have been investigated using pH-metry in aqueous medium at 25Β±1 Β° and 1 = 0.1 M NaCIO4 and EPR in frozen aquo-methanol (1:1) at 77 K. The experimental data have provided evidence for the fo