✍ Scribed by Joachim Wachter
No coin nor oath required. For personal study only.
A wide range of chemical compounds is spanned by heteroatomic ligands from Group 15/16 elements, which in Nature extend from AsS (in realgar) to [AsS ] (in sulfosalt minerals). The stabilization of labile molecules or those that do not exist in the free state by incorporation into transition metal complexes like [Cp Fe (AsSe) ] (1) and the oligomerization of molecular units under the influence of metal ions or complexes to form solids or hybrid clusters with inorganic cores and peripheral organometallic ligands are the main subjects of this article. Cp*=C Me .
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## Abstract ^207^Pb solid‐state NMR studies have been conducted on binary lead‐group 16 and mixed transition‐metal/lead group 16 materials, correlating the NMR chemical shifts of the materials with their structures. The experimental results show that the ^207^Pb chemical shifts are strongly influen