Mixed-ligand complex formation of (2,2′,2″-terpyridine)copper(I) and (2,2′2″-terpyridine)copper(II) with some sulfur-containing amino acids
✍ Scribed by Whei -Lu Kwik; Kok -Peng Ang
- Publisher
- Springer
- Year
- 1985
- Tongue
- English
- Weight
- 590 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0340-4285
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📜 SIMILAR VOLUMES
Facile reaction of 2,2',6',2"-terpyridine (L; terpy) with copper or zinc powders or their mixtures, in the presence of an excess of H202, leads to novel complexes [Cu(L)-(O 2-)-1-3H20 , [Zn(L)(O~-)-1-H20 and [Cu, Zn(L)2(O 2-)2]-4H20, respectively, which were isolated and characterized by elemental a
## Abstract [2]Rotaxanes based on the 1,2‐bis(pyridinium)ethane⊂[24]crown‐8 ether motif were prepared that contain a terminal terpyridine group for coordination to a transition‐metal ion. These rotaxane ligands were utilized in the preparation of a series of heteroleptic [Ru(terpy)(terpy–rotaxane)]