Mixed-ligand CoII and CdII complexes with 4-aminoantipyrine
β Scribed by Wang, Qian; Wu, Ming-Jie; Yang, En-Cui; Wang, Xiu-Guang; Zhao, Xiao-Jun
- Book ID
- 115502110
- Publisher
- Taylor and Francis Group
- Year
- 2008
- Tongue
- English
- Weight
- 621 KB
- Volume
- 61
- Category
- Article
- ISSN
- 0095-8972
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## Abstract Hydrothermal reactions of Cd^II^, Co^II^, and Mn^II^ with the mixed ligands 3,4βpyridinedicarboxylate (pydc), 1,3βbis(4βpyridyl)propane (bpp), or 1,2βbis(4βpyridyl)ethane (bpe) gave crystals of {[Cd(pydc)(bpp)]Β·0.5H~2~O}~__n__~ (1), {[Co(pydc)(H~2~O)(bpe)~0.5~]Β·0.5H~2~O}~__n__~ (2), and
In the crystal structure of the centrosymmetric title complex, bis the Mn atom adopts a trigonal-bipyramidal geometry and the ligand adopts two coordination modes, monodentate and bidentate bridging.