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Mixed Isobutylphobane/N-Heterocyclic Carbene Ruthenium- Indenylidene Complexes: Synthesis and Catalytic Evaluation in Olefin Metathesis Reactions

✍ Scribed by Xavier Sauvage; Guillermo Zaragoza; Albert Demonceau; Lionel Delaude


Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
419 KB
Volume
352
Category
Article
ISSN
1615-4150

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## Abstract Mixed N‐heterocyclic carbene‐substituted phosphine and phosphite complexes of rhodium were prepared, starting from [Rh(COE)~2~Cl]~2~ (COE=cyclooctene) by addition of free N‐heterocyclic carbenes (NHC) and PR~3~. All new complexes were characterized by spectroscopy. In addition, the stru