Mixed crystal of bis(μ2-N,N-di-n-butyldithiocarbamato-S,S,S′)-bis(N,N-di-n-butyldithiocarbamato-S,S′)-di-zinc(II) and bis(μ2-N,N-di-n-butyldithiopercarbamato-S,O,O′)-bis(N,N-di-n-butyldithiocarbamato-S,S′)-di-zinc(II)
✍ Scribed by F. Emmerling; R. Becker; G. Reck
- Publisher
- John Wiley and Sons
- Year
- 2007
- Tongue
- English
- Weight
- 278 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0232-1300
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✦ Synopsis
The title compounds Zn
2 )] 2 3 build mixed crystals in the ratio 0.42 : 0.58. Each compound forms dimers, in which the monomer moieties are related via a two-fold axis, coinciding with that of the monoclinic space group C2/c. The lattice parameters are a = 23.581( ), b = 17.112(5), c = 16.372(9) Å, and β = 128.33(3) o .
📜 SIMILAR VOLUMES
The dinuclear cyclopalladated compounds [Pd(µ-Cl)Ln] 2 (2) acetato-thiolato bridged complexes [Pd 2 (µ-OAc)(µ-SRm)Ln 2 ] (4). In addition to their mesogenic behavior, the most [HLn = p-C n H 2n+1 OC 6 H 4 CH=NC 6 H 4 OC n H 2n+1 -p (n = 6, 8, and 10)] react with silver thiolates AgSRm (Rm = C m H 2m