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Mixed crystal of bis(μ2-N,N-di-n-butyldithiocarbamato-S,S,S′)-bis(N,N-di-n-butyldithiocarbamato-S,S′)-di-zinc(II) and bis(μ2-N,N-di-n-butyldithiopercarbamato-S,O,O′)-bis(N,N-di-n-butyldithiocarbamato-S,S′)-di-zinc(II)

✍ Scribed by F. Emmerling; R. Becker; G. Reck


Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
278 KB
Volume
42
Category
Article
ISSN
0232-1300

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✦ Synopsis


The title compounds Zn

2 )] 2 3 build mixed crystals in the ratio 0.42 : 0.58. Each compound forms dimers, in which the monomer moieties are related via a two-fold axis, coinciding with that of the monoclinic space group C2/c. The lattice parameters are a = 23.581( ), b = 17.112(5), c = 16.372(9) Å, and β = 128.33(3) o .


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Mesogenic Dinuclear Cyclopalladated Deri
✍ Julio Buey; Gustavo A. Díez; Pablo Espinet; Santiago García-Granda; Enrique Pére 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 463 KB

The dinuclear cyclopalladated compounds [Pd(µ-Cl)Ln] 2 (2) acetato-thiolato bridged complexes [Pd 2 (µ-OAc)(µ-SRm)Ln 2 ] (4). In addition to their mesogenic behavior, the most [HLn = p-C n H 2n+1 OC 6 H 4 CH=NC 6 H 4 OC n H 2n+1 -p (n = 6, 8, and 10)] react with silver thiolates AgSRm (Rm = C m H 2m