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Mixed cerium valence and unusual Ce–Ru bonding in Ce23Ru7Cd4

✍ Scribed by Frank Tappe; Wilfried Hermes; Matthias Eul; Rainer Pöttgen

Book ID
116574672
Publisher
Elsevier Science
Year
2009
Tongue
English
Weight
552 KB
Volume
17
Category
Article
ISSN
0966-9795

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The electronic (350-900 nm), infrared and Raman (700-30 cm-1) spectra of polycrystalline samples of the mixedvalence (Ce3'/Ce4') oxysulÐde compound were investigated. The compound is a low-gap semiconductor Ce 4 O 4 S 3 with intervalence transitions in the near-infrared (ca. 850 nm) and visible (ca.