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Missing Cyclization Pathways and New Rearrangements Unveiled in the Gold(I) and Platinum(II)-Catalyzed Cyclization of 1,6-Enynes.

✍ Scribed by Catalina Ferrer; Mihai Raducan; Cristina Nevado; Christelle K. Claverie; Antonio M. Echavarren

Publisher
John Wiley and Sons
Year
2007
Weight
54 KB
Volume
38
Category
Article
ISSN
0931-7597

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Gold(I)-Catalyzed Cyclizations of 1,6-En
Gold(I)-Catalyzed Cyclizations of 1,6-Enynes: Alkoxycyclizations and exo/endo Skeletal Rearrangements
✍ Cristina Nieto-Oberhuber; M. Paz Muñoz; Salomé López; Eloísa Jeménez-Núñez; Cris 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 111 KB 👁 1 views

The authors have recently found that the configuration of diene 64 (Ar = p-MeOC 6 H 4 ) in Scheme 6 was incorrectly assigned. The major isomer has a cis configuration, whereas the configuration of related compounds 62 and 66 (Ar = Ph and p-O 2 NC 6 H 4 ) is trans as reported. The correct configurati