The miscibility of polyvinylphenol (PVPh) or terpenephenol (TPh) with polyoxymethylene (POM) was examined by high-resolution solid-state 13 C nuclear magnetic resonance (NMR) spectroscopy. It was found that the driving force for the mixing of POM and PVPh is the hydrogenbonding interaction between t
Miscibility and Molecular Motion of PMAA/PVAc Blends Investigated by High-Resolution Solid-State CPMAS 13 C NMR
โ Scribed by Asano, Atsushi; Eguchi, Masaru; Shimizu, Miho; Kurotsu, Takuzo
- Book ID
- 124053415
- Publisher
- American Chemical Society
- Year
- 2002
- Tongue
- English
- Weight
- 98 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0024-9297
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The dynamics of amorphous aromatic polyesters consisting of poly(ethylene terephthalate) (PET), poly(ethylene isophthalate) (PEI), and poly(ethylene 2,6-naphthalenedicarboxylate) (PEN) has been investigated by means of solid state CPMAS 13 C NMR. Proton T 2 , 13 C T 1r , and proton T 1r decays have
## Variable -temperature solid-state 13C NMR measurements show effects due to molecular motion in spectra of 2,2-bis[p-(2,3-dihydroxypropoxy)phenyl]propane (BADGETOL), which is a derivative of bisphenol-A diglycidyl ether. Features in the spectra indicate that the motions present may not be charac