Millimeterwave rotational spectrum and internal rotation in o-chlorotoluene
β Scribed by K.P.R. Nair; J. Demaison; G. Wlodarczak; I. Merke
- Book ID
- 108185185
- Publisher
- Elsevier Science
- Year
- 2006
- Tongue
- English
- Weight
- 143 KB
- Volume
- 237
- Category
- Article
- ISSN
- 0022-2852
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The rotational spectra of both \(\mathrm{CH}_{2}=\mathrm{CHPH}_{2}\) and \(\mathrm{CH}_{2}=\mathrm{CHPD}_{2}\) have been measured from 8 to \(320 \mathrm{GHz}\). Rotational constants, centrifugal distortion constants, and dipole moment components have been determined. Only the gauche form (dihedral
Methyl carbamate, an isomer of glycine, is a possible candidate for interstellar detection. It might be more abundant than glycine and its dipole moment is much larger. Furthermore, using high-level quantum chemical calculations, it is shown that syn methyl carbamate has a lower energy than glycine.