✦ LIBER ✦

Millimeter-Wave Spectrum of Nitrosyl Bromide in the Low-Lying Excited States: Equilibrium Structure and Cubic Force Field

✍ Scribed by C.D. Esposti; F. Tamassia; G. Cazzoli; Z. Kisiel

Publisher: Elsevier Science
Year: 1995
Tongue: English
Weight: 755 KB
Volume: 170
Category: Article
ISSN: 0022-2852
DOI: 10.1006/jmsp.1995.1093

No coin nor oath required. For personal study only.

✦ Synopsis

The rotational spectra of ({ }^{79} \mathrm{BrNO}) and ({ }^{81} \mathrm{BrNO}) in the low-lying vibrational states (v_{2}=1, v_{3}=) 1 , and (v_{3}=2) have been observed in the frequency region (80-190 \mathrm{GHz}). The high-order Coriolis resonance between the (v_{2}=1) and (v_{3}=2) states has been taken into account in the analysis of the spectra. From the obtained results an approximate equilibrium structure has been calculated and a new evaluation of the quadratic and cubic force fields of nitrosyl bromide has been made. The experimental values of the third-rank Coriolis parameter are very well reproduced by the obtained anharmonic force field. (c) 1995 Academic Press, Inc.

📜 SIMILAR VOLUMES

The Coriolis Interaction between thev2=

The Coriolis Interaction between thev2= 1 andv3= 2 States of Nitrosyl Bromide: Anomalous Quadrupole Patterns and Interstate Transitions in the Millimeter-Wave Spectrum

✍ C.Degli Esposti; A. Fuganti; Z. Kisiel; F. Tamassia 📂 Article 📅 1998 🏛 Elsevier Science 🌐 English ⚖ 298 KB

The millimeter-wave rotational spectra of 79 BrNO and 81 BrNO in the v 2 ϭ 1 and v 3 ϭ 2 vibrational states have been reinvestigated. Measurements of the rotational spectrum in the region of maximum c-type Coriolis interaction between the two states allowed the previous analysis to be extended to ac

The Millimeter-Wave Spectrum of CF3C35Cl

The Millimeter-Wave Spectrum of CF3C35Cl237Cl in Its Ground State and the Vibrational Force Field of Trifluorotrichloroethane

✍ P.J. Seo; J.H. Carpenter; J.G. Smith 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 351 KB

The millimeter-wave rotational spectra of the ground state of the asymmetric-top species \(\mathrm{CF}_{3} \mathrm{C}^{35} \mathrm{Cl}_{2}{ }^{37} \mathrm{Cl}\) have been recorded and assigned for \(J^{\prime \prime}=30\) up to \(J^{\prime \prime}=55\) and analyzed to yield the following rotational