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Mild oxidations of coal models

✍ Scribed by John G. Huntington; Frank R. Mayo; Norman A. Kirshen

Publisher: Elsevier Science
Year: 1979
Tongue: English
Weight: 733 KB
Volume: 58
Category: Article
ISSN: 0016-2361
DOI: 10.1016/0016-2361(79)90048-6

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✦ Synopsis

Relative rates of oxidation of numerous coal models have been determined by two methods in radicalinitiated oxidationsat 50°C. The results show that hydroaromatic rings (as in 9,10-dihydroanthracene and tetralin) and some anthracenes are so much more reactive than -CH2-O-or -CH2-links between benzene rings that cleavage reactions of the latter groups would be excluded in competitive oxidation. However, similar connecting links between naphthalene or more condensed rings will be more competitive. Rates of oxidation of condensed aromatic hydrocarbons can now be related to extensive previous data on alkylbenzenes and a variety of aliphatic compounds.

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