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Mild Nonepimerizing N-Alkylation of Amines by Alcohols without Transition Metals

✍ Scribed by Guérin, Claire; Bellosta, Véronique; Guillamot, Gérard; Cossy, Janine

Book ID
115465834
Publisher
American Chemical Society
Year
2011
Tongue
English
Weight
899 KB
Volume
13
Category
Article
ISSN
1523-7060

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N-Alkylation of amines with alcohols cat
N-Alkylation of amines with alcohols catalyzed by a Cp*Ir complex
✍ Ken-ichi Fujita; Zhenzi Li; Naohiro Ozeki; Ryohei Yamaguchi 📂 Article 📅 2003 🏛 Elsevier Science 🌐 French ⚖ 493 KB

A new effective catalytic system consisting of [Cp\*IrCl 2 ] 2 /K 2 CO 3 (Cp\*=pentamethylcyclopentadienyl) for the N-alkylation of primary amines with alcohols has been developed. As an example, the reaction of aniline with benzyl alcohol in the presence of [Cp\*IrCl 2 ] 2 (5.0 mol%Ir) and K 2 CO 3