𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Mild conversion of primary alcohols and aldehydes to acid fluorides with caesium fluoroxysulphate

✍ Scribed by Stojan Stavber; Zdenka Planinšek; Marko Zupan

Publisher
Elsevier Science
Year
1989
Tongue
French
Weight
172 KB
Volume
30
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

✦ Synopsis

Caesium fluoroxysulphate in acetonitrile medium at 39C converts primary alcohols and alkyl, as well as aryl aldehydes, to acid fluorides in high yield.

📜 SIMILAR VOLUMES

IBX-Mediated Conversion of Primary Alcoh
IBX-Mediated Conversion of Primary Alcohols and Aldehydes to N-Hydroxysuccinimide Esters
✍ Agnes Schulze; Athanassios Giannis 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 117 KB 👁 2 views

## Abstract Recently, the use of the hypervalent iodine reagent 1‐hydroxy‐1,2‐benziodoxol‐3(1__H__)‐one 1‐oxide (IBX) for the oxidation of primary alcohols and aldehydes to carboxylic acids was described. During the synthesis of these carboxylic acids the corresponding __N__‐hydroxysuccinimide este