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Mild and Reversible Friedel-Crafts Acylation: Synthesis of 6-Acyl-2-methoxynaphthalenes

✍ Scribed by Giordano, Claudio ;Villa, Marco ;Annunziata, Rita


Book ID
120384332
Publisher
Taylor and Francis Group
Year
1990
Tongue
English
Weight
340 KB
Volume
20
Category
Article
ISSN
0039-7911

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MCM-41 type molecular sieves as catalyst
✍ Eric A. Gunnewegh; Saritha S. Gopie; Herman van Bekkum 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 660 KB

Molecular sieves of the MCM-41 type were studied as catalysts for the Friedel-Crafts acylation of 2-methoxynaphthalene in the liquid phase. When MCM-41 in the H+ form is used as Bronsted-acid catalyst, acylation with acetic anhydride gives substitution predominantly at the l-position. Increased reac