## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v
Mild and practical stereoselective synthesis of (Z)- and (E)-allyl bromides from Baylis–Hillman adducts using Appel agents (PPh3/CBr4): a facile synthesis of semiplenamides C and E
✍ Scribed by Biswanath Das; Kongara Damodar; Nisith Bhunia; Boddu Shashikanth
- Publisher
- Elsevier Science
- Year
- 2009
- Tongue
- French
- Weight
- 223 KB
- Volume
- 50
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
Appel agents (PPh 3 /CBr 4 ) have been utilized for high-yielding stereoselective synthesis of (Z)-and (E)allyl bromides from Baylis-Hillman adducts at room temperature. The method has been applied for the synthesis of naturally occurring bioactive fatty acid amides, semiplenamides C and E.
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v
Treatment of Baylis-Hillman adducts 1 with bromo(dimethyl)sulfonium bromide, Br(Me 2 )S + Br À , in MeCN was found to stereoselectively afford (Z)-and (E)-allyl bromides 2. The reaction is rapid at room temperature, high-yielding, and highly stereoselective.
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v