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Mild and High-Yielding Syntheses of Diethyl Phosphoramidate-Stoppered [2]Rotaxanes †

✍ Scribed by Hung, Wei-Chung; Liao, Kang-Shyang; Liu, Yi-Hung; Peng, Shie-Ming; Chiu, Sheng-Hsien


Book ID
121080335
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
88 KB
Volume
6
Category
Article
ISSN
1523-7060

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High Yielding Template-Directed Synthese
✍ José A. Bravo; Françisco M. Raymo; J. Fraser Stoddart; Andrew J. P. White; David 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 331 KB 👁 2 views

Three dumbbell-shaped compounds incorporating terminal chains of the templates influences the efficiencies of the template-directed syntheses. Rotaxane formation occurs only triisopropylsilyl stoppers, connected to a central 1,5dioxynaphthalene recognition site by [-CH 2 CH 2 O-] n spacers if n Ͼ 1