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Migratory Transmetalation in Diphenoxo-Bridged Cu II M II Complexes of a Dinucleating Macrocycle with N(amine) 2 O 2 and N(imine) 2 O 2 Metal-Binding Sites

✍ Scribed by Yonemura, Masami; Matsumura, Yukiko; Furutachi, Hideki; Ohba, Masaaki; Ōkawa, Hisashi; Fenton, David E.


Book ID
127095635
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
203 KB
Volume
36
Category
Article
ISSN
0020-1669

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## Abstract A pentadentate phenol‐containing ligand (H~3~L) with N~2~O~3~ donor atoms yields Ni^II^~2~ (1), Ni^II^~4~ (2), Cu^II^~2~ (3) and Cu^II^~4~ (4) complexes, which have been structurally characterized by X‐ray diffraction. Complex 1 contains a single‐atom __O__‐bridged urea. The compounds w